寧夏大學化學化工學院物理化學研究生導師：劉翔宇

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1.個人簡歷：

2008年07月-至今，寧夏大學化學化工學院副教授/碩導

2018年05月-2019年05月，University of Valencia國家留學基金委(CSC)訪問學者

2012年09月-2015年06月，西北大學化學與材料科學學院材料化學博士

2005年09月-2008年07月，寧夏大學化學化工學院物理化學碩士

2000年09月-2004年07月，寧夏大學化學化工學院化學工程與工藝學士

2. 主要研究方向及成果：

主要研究方向包括：1)分子基磁性材料的構筑、表征及應用;2)高能密度材料的制備及理化性能研究;3)多孔金屬有機框架材料(MOFs)的合成及性能研究。

在Coordin. Chem. Rev.、Chem. Commun.、Green Chem.、Chem. Eur. J.、Inorg. Chem.、J. Phys. Chem. C、J. Mater. Chem. A、Dalton Transa

ctions、New J. Chem. 等主流源期刊發表SCI論文50余篇(通訊或第一作者28篇，1篇論文入選ESI前3%高被引論文)，在《化學教育》等期刊發表教改論文2篇。目前主持在研國家自然科學基金項目2項、寧夏高等學校優秀青年培育項目1項、省部共建國家重點實驗室開放課題1項、寧夏大學一流學科建設項目1項、主持及參與完成寧夏自然科學基金項目2項、寧夏高等學校科學研究項目1項、寧夏大學科學研究項目2項，主持區級教改項目1項，指導國家級、自治區級大學生創新實驗項目3項。2016年，主編出版學術著作1部，2018年，授權發明專利1項。2014年，榮獲陜西省首屆研究生創新成果展“優秀獎”(排名第一);榮獲2015屆西北大學優秀博士學位畢業論文。2017年，榮獲寧夏優秀自然科學論文二等獎、三等獎各1項。2018年，入選第三批“寧夏青年科技人才托舉工程”人選。

發表論文(第一或​通訊作者)：

1. Peipei Cen,XiangyuLiu,*JesúsFerrando-Soria, Yi-Quan Zhang, GangXie, Sanping Chen,*Emilio Pardo. Capping N-Donor Ligands Modulate the Magnetic Dynamics of β-Diketonate-DyIII Single-Ion Magnets with D4d Symmetry. Chemistry–A European Journal, 2018, DOI: 10.1002/chem.201805608.

2.XiangyuLiu,*Xiufang Ma, Weize Yue, Peipei Cen, Yi-QuanZhang.*Jesus.Ferrando-Soria, Sanping Chen,Emilio Pardo. Concise Chemistry Modulation of the SMM Behavior within a Family of Mononuclear Dy(III) Complexes. Inorg. Chem., 2018, 57, 14843-14851.

3.PeipeiCen, WeizeYuan, MengyaoTan, BingbingChen, WeimingSong, ZhengWang,XiangyuLiu*. Field-induced slow magnetic relaxation in an octahedral high-spin Co(II) complex. Inorganic Chemistry Communications. 2018, 99, 195-198.

4.Xiaohui Ma,Yaru Liu,Weiming Song, Zheng Wang, XiangyuLiu,* Gang Xie, Sanping Chen, Shengli Gao. A difunctional azido-cobalt(ii) coordination polymer exhibiting slow magnetic relaxation behaviour and high-energy characteristics with good thermostability and insensitivity. Dalton Transactions, 2018, 47, 12092-12104.

5.XiangyuLiu,*Xiufang Ma, Peipei Cen, Fengqing An, Zheng Wang, Weiming Song, Yi-QuanZhang.*

One-dimensional cobalt(II) coordination polymer featuringsingle-ion-magnet-type field-induced slow magneticrelaxation. New Journal of Chemistry, 2018, 42, 9612-9619.

6. Zhao Xu, Fengqin An, Xiaohui Ma, Huiliang Zhou, Weiming Song, XiangyuLiu.* Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability. ZeitschriftfürNaturforschung B, 2018, 73(5), 311-317.

7. Haiwen Wei, Qingfeng Yang*,Xiaoyong Lai, Xiaozhong Wang, Tianlin Yang, Qin Hou, Xiangyu Liu*. Field-Induced Slow Relaxation of the Magnetization in a Distorted Octahedral Mononuclear High-Spin Co(II) Complex. CrystEngComm, 2018,20(7), 962-968.

8.Xiaohui Ma, Yuewei Wu, Peipei Cen, Shenru Ma, Chengcheng Zhang, Shuchang Luo, Huiliang Zhou, Weiming Song, XiangyuLiu.* Ferromagnetic ordering and slow magnetic relaxation observed in a triple-bridged azido-Cu(II) chain compound with mixed carboxylate/ethanol linkers. New Journal of Chemistry, 2017, 41, 9631-9638.

9.XiangyuLiu,*Xiaohui Ma, Peipei Cen, Yuewei Wu, Chengcheng Zhang, Quan Shi,* Weiming Song, Gang Xie, Sanping Chen. A Substituent effect of phenylacetic acid coligands perturbed structures and magnetic properties observed in two triple-bridged azido-Cu (II) chain compounds with ferromagnetic ordering and slow magnetic relaxation. Dalton Transactions, 2017, 46, 7556-7566.

10. XiangyuLiu,* Pei-Pei Cen, Li-Zhou Wu, Feifei Li, Wei-Ming Song, Gang Xie, San-Ping Chen*. Tuning of Exchange Coupling and Switchable Magnetization Dynamics by Displacing the Bridging Ligands Observed in Two Dimeric Manganese (III) Compounds. Scientific Reports, 2017, 2017, 7, 44982-44990.

11. Pei-Pei Cen, Sheng Zhang, XiangyuLiu,* Wei-Ming Song, Yi-Quan Zhang,* Gang Xie, San-Ping Chen*. Electrostatic Potential Determined Magnetic Dynamics Observed in Two Mononuclear β‑Diketone Dysprosium(III) Single-Molecule Magnets. Inorg. Chem., 2017, 56, 3644-3656.

12. XiangyuLiu,*Feifei Li, Xiaohui Ma, Peipei Cen, Shuchang Luo, Quan Shi, Shenru Ma, Yuewei Wu, Chengcheng Zhang, Zhao Xu, Weiming Song, Gang Xie, Sanping Chen. Coligand modifications fine-tuned the structure and magnetic properties of two triple-bridged azido-Cu(II) chain compounds exhibiting ferromagnetic ordering and slow relaxation. Dalton Transactions, 2017, 46, 1207–1217.

13. Yuewei Wu, Chengcheng Zhang, Zhao Xu, Chao Cai, Weiming Song, Xiaoying Zhang, Yangyang Tian, Xiangyu Liu*. Two new cobalt-organic frameworks constructed from polycarboxylates and pyridine-triazole ligands: Synthesis, crystal structures and magnetic properties. Inorg. Chem. Commun., 2017, 84, 190-194.

14. Xiaohui Ma, Feifei Li, Peipei Cen, XiangyuLiu,*Huiliang Zhou, Shuchang Luo, Yuewei Wu, Chengcheng Zhang, Weiming Song. One-dimensional Cu(II) chain compound with simultaneous EO-azido and carboxylato bridges displaying strong ferromagnetic coupling: synthesis, crystal structure, magnetic properties with DFT calculations. Chinese journal of inorganic chemistry. 2017, 33, 1639-1648.

15.Xiangyu Liu*, Peipei Cen, Feifei Li, Xiaohui Ma, Huiliang Zhou, Xiaoyan Chen, Weiming Song, Gang Xie, Sanping Chen.

A unusual two-dimensional azido-Cu(II) network with benzoate derivative as coligand exhibiting ferromagnetic order and slow magnetic relaxation. RSC Adv, 2016, 6, 96103-96108.

16. Xiangyu Liu*, Huaixian Liu, Peipei Cen, Xiaoyan Chen, Huiliang Zhou, Weiming Song, QilinHu. Auxiliary ligand-triggered assembly of two dinuclearCu(II) compounds with a pyridylhydrazone derivative: Synthesis, crystal structure and magnetic property. Inorg. Chim. Acta, 2016, 447, 12-17.

17. Xiangyu Liu*, Lin Sun, Huiliang Zhou, Peipei Cen, XiaoyongJin, Gang Xie, Sanping Chen, Qilin Hu.

Single-Ion-Magnet Behavior in a Two-Dimensional Coordination Polymer Constructed from CoII Nodes and a Pyridylhydrazone Derivative.

Inorg. Chem., 2015, 54, 8884–8886.

18. Xiangyuliu, Wenjuan Gao, Panpan Sun, ZhiyongSu, SanpingChen,* Qing Wei, Gang Xie, Shengli Gao. Environmentally-friendly high-energy MOFs: crystal structure, thermostability, insensitivity and remarkable detonation performance.

Green Chem., 2015, 17, 831-836.

19. Xiangyu Liu, Xiaoni Qu, Sheng Zhang, HongshanKe, Qi Yang, Quan Shi, Qing Wei, Gang Xie, Sanping Chen*. High-Performance Energetic Characteristics and Magnetic Properties of a Three-Dimensional Cobalt (II) Metal–Organic Framework Assembled with Azido and Triazole. Inorg. Chem., 2015, 54(23), 11520–11525.

20. Xiangyu Liu*,Peipei Cen, Huiliang Zhou, XiaoyongJin, Qilin Hu, Yongqiang Ji.

A new 3D Cd(II) metal–organic framework with discrete (H2O)6clusters based onflexible cyclohexane-1,2,4,5-tetracarboxylic acid ligand. Inorg. Chem. Commun., 2015, 53, 11–14.

21.Lin Sun, Huaixian Liu, Huiliang Zhou, Xiangyu Liu*,Weiming Song, Bing Li, Qilin Hu. A Cobalt(II) Coordination Compound with 1H-3-(3-pyridyl)-5-(3′-pyridyl)-1,2,4-triazole: Synthesis, Crystal Structure, Thermostability and DFT Calculation of Ligand.

Chinese journal of inorganic chemistry. 2015, 31, 1207-1214.

22. Xiangyu Liu*, Huaixian Liu, Huiliang Zhou, Peipei Cen, XiaoyongJin, Weiming Song, Shuchang Luo, Qilin Hu. A new cobalt(II)-containing coordination polymer composed of dinuclear metal units: synthesis, crystal structure and magnetic property with DFT calculation.

Canadian Journal of Chemistry, 2015, 93(11), 1214-1218.

23. Huaixian Liu, Lin Sun, Huiliang Zhou, Peipei Cen, XiaoyongJin, Xiangyu Liu*, Qilin Hu.

A mononuclear cobalt(III) 3-(2-pyridyl)-5-phenyl-1,2,4-triazolato complex: hydrothermal synthesis, crystal structure, thermostability, and DFT calculations. Zeitschrift fur naturforschung section b, 2015, 70(9), 631-636.

24. Xiangyu Liu, Peipei Cen, Hui Li, HongshanKe, Sheng Zhang,Qing Wei, Gang Xie, Sanping Chen,* Shengli Gao.

Solvent-Induced Syntheses, Crystal Structures, Magnetic Properties and Single-Crystal-to-Single-Crystal Transformation of Azido-Cu(II) Coordination Polymers with 2-Naphthoic Acid as Coligand. Inorg. Chem.,

2014, 53 (15), 8088–8097.

25. Xiangyu Liu, ZhiyongSu, Wenxin Ji, SanpingChen,* Qing Wei, Gang Xie, Xuwu Yang, Shengli Gao.

Structure, Physicochemical Properties, and Density Functional Theory Calculation of High-Energy-Density Materials Constructed with Intermolecular Interaction: Nitro Group Charge Determines Sensitivity. J. Phys. Chem. C, 2014, 118, 23487−23498.

26.Xiangyu Liu, SanpingChen,* Thais Grancha, Emilio Pardo,* HongshanKe, Bing Yin, Qing Wei, Gang Xie, Shengli Gao.

A triple-bridged azido-Cu(II) chain compound fine-tuned by mixed carboxylate/ethanol linkers displays slow-relaxation and ferromagnetic order: synthesis, crystal structure, magnetic properties and DFT calculations. Dalton Trans., 2014, 43, 15359–15366.

27. Xiangyu Liu, Qi Yang, ZhiyongSu, SanpingChen,* Gang Xie, Qing Wei, Shengli Gao.

3D high-energy-density and low sensitivity materials: synthesis, structure and physicochemical properties of an azide–Cu(II) complex with 3,5-dinitrobenzoic acid. RSC Adv., 2014, 4, 16087–16093.

28. XiangyuLiu, LinqiangDuan, Qing Wei, Sanping Chen.*

Two cyanide-bridged compounds composed of Schiff base–manganese(III) building block with dicyanamido and hexacyanocobaltate(III) as ligands: Crystal structure, thermostability and magnetic property.

Inorg. Chim. Acta, 2014, 423, 462–468.