華東理工大學

華東理工大學化學與分子學院碩士研究生導師信息介紹：王利民

一、個人簡況

王利民（Wang Limin），教授，博士生導師。

大連理工大學應用化學(精細化工)博士，美國康乃爾大學（Cornell）訪問學者。

華東理工大學化學與分子工程學院精細化工系主任，“皮革化學與工程”博士點以及“輕工技術與工程”工程碩士點的導師組組長。

聯系方式：上海市梅隴路130號，電話：021-64253881，64252758，64252288，郵編：200237

郵件：wanglimin@ecust.edu.cn

二、研究領域與研究方向、學術團體兼職情況

1．基礎研究：金屬有機化學(稀土金屬有機化學、合成方法學)、有機氟化學（含氟材料）和精細化學品化學（染料、顏料、表面活性劑）

2．應用研究：(1)精細化學品合成（染料、顏料及其中間體、醫藥中間體、精細有機中間體、功能材料等），(2)表面活性劑及其助劑合成（日用化學品、醫藥助劑、紡織助劑、輕工助劑、有機硅氟表面活性劑等）

至今已在J. Org. Chem., Adv. Synth.Catal.等國際核心刊物上發表50余篇論文，共被他人引用650余次，單篇最高95次，其中2005年發表于Tetrahedron (Volume61, 6(2005), Pages 1539-1543)的文章獲得Tetrahedron Most Cited Paper 2005-2008 Award。申請中國發明專利37項，其中16項已授權。出版有關論（譯）著（包括參編或參譯）6部。

三、學術團體兼職

美國化學學會會員

中國化工學會精細化工專業委員會委員

全國稀土助染助鞣協作網專家組成員

“應用化學”，“精細化工”，“中國皮革”雜志編委

徐匯區青年科技工作者聯誼會理事

四、代表性論文及論著

1. Limin Wang*, Jianjun Xia, He Tian, Fang Qin, Changtao Qian, Jie Sun, Yb(OTf)3 Catalyzed One-Pot Synthesis of Quinazolin-4(3H)-ones from anthranilic acid, amine and orthoesters (or formic acid)  in Solvent-free Conditions. Synthesis, 2003, 8, 1241-1247.

2. Limin Wang*, Changtao Qian, He Qian,Yun Ma, Lanthanide Triflate Catalyzed One-Pot Synthesis of Dihydropyrimidin-2(1H)-thiones by a Three-Component of 1,3-Dicarbonyl Compounds, Aldehydes, and Thiourea Using a Solvent-free Biginelli Condensation,   Synthetic Communications, 2003, 33(9), 1459-1468.

3. Limin Wang*, Jianjun Xia, He Tian, Changtao Qian, Yun Ma, Synthesis of coumarin by Yb(OTf)3 catalyzed Pechmann reaction under the solvent-free conditions, Indian Journal of Chemistry, Section B, 2003, 42B, 2097-2099.

4. Limin Wang*，Jijun Liu, He Tian, Changtao Qian, Ytterbium Triflate Catalyzed Heterocyclization of 1, 2-Phenylenediamines and Alkyloxalates under Solvent-Free Conditions via Phillips Reaction: a facile Synthesis of Quinoxaline-2, 3-diones derivatives. Synth. Commun. 2004, 34, 1349-1355.

5. Limin Wang*, Jia Sheng, He Tian, Jianwei Han, Zhaoyu Fan, Changtao Qian, A Convenient Synthesis of α, α’-Bis(substituted benzylidene)cycloalkanones Catalyzed by Yb(OTf)3 Under Solvent-free Conditions. Synthesis, 2004, 18, 3060-3064.

6. Limin Wang*, Jia Sheng, He Tian, Changtao Qian, An efficient procedure for the synthesis of Benzimidazole derivatives using Yb(OTf)3 as catalyst under solvent-free conditions. Synthetic Communication, 2004, 34(23), 4265-4272.

7. Limin Wang*, Jijun Liu, He Tian, Changtao Qian, Jie Sun, One-pot Synthesis of cis-Isoquinolonic acids derivatives via three-component Reaction of Homophthalic Anhydride with Aldehydes and Amines Using Ytterbium(Ⅲ) Triflate as a Catalyst, Adv. Synth. Catal. 2005, 347(5), 689-694.

8. Limin Wang, Jianwei Han, He Tian, Jia Sheng, Zhaoyu Fan, Xiaoping Tang, Rare earth Perfluorooctanoates[RE(PFO)3]-catalyzed Condensations of Indole with Carbonyl Compounds, Synlett, 2005, 2, 0337-0339.

9. Limin Wang*, Jianwei Han, Jia Sheng, He Tian, Zhaoyu Fan,  Rare earth Perfluorooctanoate [RE(PFO)3] catalyzed one-pot Mannich reaction: Three component synthesis of β-Amino carbonyl compounds, Catalysis communications, 2005, 6(3), 201-204.

10. Limin Wang*, Jia Sheng, Liang zhang, Jianwei Han, Zhao-Yu Fan, He Tian, Facile Yb(OTf)3 Promoted One-Pot Synthesis of Polyhydroquinoline Derivatives Through Hantzsch Reaction. Tetrahedron, 2005, 61(6), 1539-1543.

11. Li-Min Wang*, Jue-Hua Shao, He Tian, Yong-Hong Wang, Bo Liu，Rare Earth Perfluorooctanoate [RE(PFO)3] Catalyzed One-pot Synthesis of Benzopyran Derivatives， Journal of Fluorine Chemistry，2006，127(1)，97-100.

12.Li-Min Wang*, Yong-Hong Wang, He Tian, Yin-fang, Yao, Jue-Hua Shao, Bo Liu, Ytterbium triflate as an efficient catalyst for one-pot synthesis of substituted imidazoles through three-component condensation of benzil, aldehydes and ammonium acetate, Journal of Fluorine Chemistry，2006，127(12)，1570-1573.

13. Yun Ma, Limin Wang*, Juehua Shao, He Tian, Recent Developments of Lewis Acids Catalysis: Lanthanide Catalysts with Long Perfluoro-Chain in Organic, Current Organic Chemistry, 2007, 6(11), 559-576. (IF3.961)

14. Wang, Limin*, Pan Xiaojuan, Fan, Zhaoyu, Yang, Liubo, Liu Lian, Tian, He, Synthesis and Crystal Structure of 4,4'-Diamino-N,N'-diethyl bisbenzenesulfamide, Chinese J. Struct. Chem. 2007, 26, 177-183.

15.Wang, Li-Min* Zhang, Liang, Hu, Liang, Tian, He, Highly One-Pot Synthesis of 2-Arylmethyl-N-Substituted Anilines via Yb(OTf)3 Catalyzed Three-component Reaction, Chinese Journal of Chemistry, 2007, 3(25), 370-374.

16. Limin Wang, Xiaojuan Pan, Feng Wang, He Tian, Liubo Yang, Lian Liu, Structure-properties relationships investigation on the azo dyes derived from benzene sulfonamide intermediates, Dyes and pigments, 2008, 76, 636-645.

17. Wei Shen, Li-Min Wang*, Jian-Jun Feng, He Tian, Highly efficient synthesis of homoallylic alcohols and amines via allylation of aldehydes and imines catalyzed by ZrOCl28H2O in water, Tetrahedron Lett. 49(25), 2008, 4047–4049.

18. Jie Wu, Li-Min Wang*, Ping Zhao, FengWang, Gui-fengWang, A new type of quaternary mmonium salt containing siloxane group and used as favorable dispersant in the surface treatment of C.I. pigment red 170, Progress in Organic Coatings  2008, 63, 189–194.

19. Wei Shen, Li-Min Wang*, He Tian, Quaternary ammonium salt gemini surfactants containing perfluoroalkyl tails catalyzed one-pot Mannich reactions in aqueous media, Journal of Fluorine Chemistry 2008, 129(4), 267–273.

20. Li-Min Wang*, Liang Hu, Jue-Hua Shao, Jianjun Yu, Liang Zhang, A novel catalyst zinc(II)        perfluorooctanoate [Zn(PFO)2]-catalyzed three-component one-pot eaction: Synthesis of quinazolinone derivatives in aqueous micellar media, Journal of Fluorine Chemistry, 2008, 129(12), 1139-1145

21.Wang Li-Min*, Sui Yuan-Yuan, Zhang Liang,  Synthesis of 14-alkyl or aryl-14-H-dibenzo[a,j]xanthenes using Yb(OTf)3 as an efficient catalyst under solvent-free conditions, Chinese Journal of Chemistry, 2008, 26(6), 1105-1108.

22. Li-Min Wang*, Liang Hu, Hong-Juan Chen, Yuan-Yuan Suia, Wei Shen, One-Pot Synthesis of Quinoline-4-carboxylic acid derivatives in water: Ytterbium Perfluorooctanoate Catalyzed Doebner Reaction, Journal of Fluorine Chemistry, 2009, 130(4), 406-409.

23. WANG, Li-Min*, YAO, Yin –Fang,  WANG, Yong-Hong, ZOU, Gang, A highly efficient and environmentally friendly CMC-supported lanthanide catalyst for one-pot synthesis of substituted imidazoles, Chinese Journal of Chemistry, 2009, 27(2), 343-346.

24. Wei Shen, Li-Min Wang*, He Tian, Jun Tang, Jian-jun Yu, Brønsted acidic ionic liquid containing perfluoroalkyl tails catalyzed one-pot synthesis of 1,8-dioxo-decahydroacridines in water, Journal of Fluorine Chemistry, 2009, 130(6), 522-527.

25. Li-Min Wang*, Ning Jiao, Jun Qiu, Jian-Jun Yu, Jin-Qian Liu, Feng-Lou Guo, Ying Liu,    Sodium stearate catalyzed multicomponent reactions for efficient synthesis of spirooxindoles in aqueous micellar media, Tetrahedron, 2010, 66(1) , 339–343.

26. Jian-Jun Yu, Li-Min Wang,* Jin-Qian Liu, Feng-Lou Guo, Ying Liu and Ning Jiao, Synthesis  of tetraketones in water and under catalyst-free conditions, Green Chem., 2010, 12, 216-219.

27. Shen, Wei, Wang, Limin*, Tang, Jun,Qian, Zhenhua,  Tong, Xiaofeng,

Ionic Liquid-coordinated Ytterbium(III) Sulfonate Catalyzed Michael Addition of Indoles to Electron-deficient Nitroolefins, Chinese Journal of Chemistry, 2010, 28, 443-448.

28.Liu, Y.; Wang, L. M*; Sui, Y. Y.; Yu, J. J. Solvent-free Synthesis of Alkylaminophenols via Petasis Boronic Mannich Reaction in One Pot without Catalysts,  Chin. J. Chem. 2010, 28, 2039-2044.

29.Jun Tang , Limin Wang*, Yinfang Yao , Liang Zhang , Wenbo Wang, One-pot synthesis of 2-amino-3-cyanopyridine derivatives catalyzed by ytterbium perfluorooctanoate [Yb(PFO)3]. Tetrahedron Letters,  2011, 52, 509–511

30. Jun Tang, Limin Wang*, WenboWang, LiangZhang, ShengyingWu, DanMao. A facile synthesis of α-aminophosphonates catalyzed by ytterbium perfluorooctanoate under solvent-free conditions. Journal of Fluorine Chemistry, 2011,132, 102-106

31.Jian-Jun Yu, Li-Min Wang,* Feng-Lou Guo, Jin-Qian Liu, Ying Liu,Ning Jiao, Solvent-free Amination of Secondary Benzylic Alcohols with N-Nucleophiles Catalysed by FeCl3, Synthetic Communications, 2011,44(11), 1609-1616

32. Jun Tang, Limin Wang,* Dan Mao, Wenbo Wang, Liang Zhang, Shengying Wu andYongshu Xie,Ytterbium Pentafluorobenzoate as a Novel Fluorous Lewis Acid Catalyst in the Synthesis of 2,4-Disubstituted Quinolines, Tetrahedron,  2011, 67, 8465–8469

33. Jun Tang, Limin Wang*, Shengying Wu, Dan Mao, The advance and application of rare earth perfluorooctanoate [RE(PFO)3], Synlett, 2011, 011， DOI: 10.1055/s-0031-1289558，ASAP

34. Jun Qiu, Limin Wang* , Mingtao Liu, Qiang Shen, Jun Tang, An efficient and simple protocol for a PdCl2-ligandless and additive-free Suzuki coupling reaction of aryl bromides,Tetrahedron Letters, 2011,52 ,6489-6491.

相關論（譯）著：

1.《精細有機合成新方法》，王利民，田禾，ISBN7-5025-5198-0/TQ.1925，化學工業出版社，2004年3月出版。

2.《分子器件與分子機器》(Molecular Devices and Machines),V. Balzani等著，田禾，王利民譯，ISBN7-5025-6857-3/O.1111,化學工業出版社，2005年6月出版。

3.《應用化學與技術》，現代工程科學與技術叢書，袁渭康總主編，田禾主編，王利民 副主編，ISBN978-7-03-019071-0, 科學出版社，2007年7月出版。

4.《Flourine Chemistry Research Advances》, Editor: Ira V. Gardiner, Chapter 5(Rare Earth Catalysts with Long Perfluoro-chain in Organic Chemistry), Li-Min Wang, Yin-Fang, Yao, Gang Zou, He Tian, ISBN 978-1-60021-730-2, © 2007 Nova Science Publishers, Inc.

5.《精細有機合成工藝》，王利民，鄒剛等，ISBN7-5025-5198-0/TQ.1925，化學工業出版社，
2008年1月出版。

6. Advances in Chemistry Research. Volume 7,   Editors: James C. Taylor,Ytterbium: Compounds, Production and Applications, chapter 4, page 127-170, Li-Min Wang, Jun Tang, Jin- Qian Liu, ISBN: 978-1-61122-211-1,© 2011 Nova Science Publishers, Inc.

五、科研項目

1、國家自然科學基金

2、中科院上海有機化學研究所有機氟化學重點實驗室開放基金

3、省部攻關項目及國內外大型精細化工和日化企業合作項目

六、部分授權專利：
 
中國 200410024683.0 ZL200410024683.0 含稀土金屬的全氟羧酸路易酸催化劑及其制備方法

中國 02151141.1 ZL 02151141.1 一種喹唑啉-4(3H)衍生物的合成方法

中國 200510112349.5 ZL 200510112349.5 陽離子型含氟Gemini表面活性劑

中國 02151142.X ZL 02151142.X 一種無致癌性的單偶氮酸性藍染料及其應用

中國 02136615.2 ZL 02136615.2 一種有機硅陰離子表面活性劑及其合成方法

中國 200410025014.5 ZL200410025014.5 陽離子、反應型有機硅固色劑及其制備方法

中國 200410079059.0 ZL200410079059.0 一種無致癌性的單偶氮酸性藍染料及其應用

中國 200610147828.5 ZL200610147828.5 陽離子型Gemini表面活性劑

中國 200610147830.2 ZL200610147830.2 稀土化合物在酰氯化反應中的應用

中國 200710045977.5 ZL200710045977.5 含硅氧鏈有機硅化合物及其用途

中國 200810040167.5 ZL 200810040167.5 無醛有機硅固色劑

中國 200810062645.2 ZL 200810062645.2 一種陰離子改性氨基硅油織物柔軟劑及其制備方法

中國 200810204944.5 ZL200810204944.5 樹枝狀稀土金屬配合物

中國 201010023011.3 ZL201010023011.3 含氟聚硅氧烷及其用途

七、研究生培養

碩士點、博士點招生：應用化學，皮革化學與工程，精細合成化學與分子工程

工程碩士點招生：輕工技術與工程，制藥工程

研究生優秀論文:

(1)劉驥軍，論文題目：稀土化合物在有機合成中的應用，2005年上海市優秀碩士論文。

(2)盛  佳，論文題目：三氟甲磺酸稀土化合物在有機合成中的應用，2006年上海市優秀碩士論文。

(3)韓建偉，論文題目：新型全氟羧酸稀土催化劑的制備及其在有機合成中應用，2007上海市優秀碩士論文。

(4)潘笑娟，論文題目：磺酰胺系中間體及其偶氮染料的合成與性能研究, 2008上海市優秀碩士論文。

(5)胡亮，全氟辛酸金屬鹽及其在含水體系中催化的有機合成反應的研究，2009, 華東理工大、學優秀碩士論文

八、獲獎

(1)有機光電功能材料與分子機器， 2006年度上海市科學技術獎，一等獎，獲獎號：20062038，完成人：田禾，陳彧，朱為宏，王利民，王巧純。

(2)稀土催化合成高性能有機顏料， 2008年教育部技術發明獎，二等獎，獲獎號：2008-115，完成人：田禾, 王利民, 王峰, 蘇建華, 陳立榮, 黃卓。

(3)"雙子座"(Gemini)硅氟鏈偕脂肪鏈季銨鹽的合成及應用，2009年教育部技術進步獎，二等獎，獲獎號：2009-225，完成人：田禾, 王利民, 施建剛, 李季, 王亞光, 繆惠平。

(4)高性能有機顏料制備新工藝，2009年上海市技術發明獎，二等獎，獲獎號：20093003-2-R02，完成人：田禾,王利民,王峰,陳立榮,黃卓,王桂峰,楊柳波。