河北大學

河北大學化學與環境科學學院研究生導師段小勇介紹如下：

一、個人簡介

段小勇，男，碩士研究生導師。2016年畢業于蘭州大學化學化工學院功能有機國家重點實驗室，獲理學博士學位，師從韓丙教授，研究方向為自由基化學。2017年3月至2018年3月在新加坡南洋理工大學(NTU-SPMS-CBC)池永貴教授組從事博士后研究工作，研究方向為不對稱有機小分子催化。并于同年9月被引

進至河北大學化學與環境科學學院工作。主要研究方向為自由基化學、不對稱催化、有機合成方法學等，已在相關研究方向發表多篇高水平SCI論文。

聯系方式：duanxy05@126.com，

實驗室：河北大學本部逸夫樓715實驗室。

歡迎對有機化學感興趣的有志人士加入我們課題組!

二、主講課程及研究方向

1.主講課程：有機化學，大學化學，基礎操作實驗，大學化學實驗，有機合成與表征實驗。

2.研究方向：自由基化學，不對稱催化，有機合成方法學，手性藥物分子合成研究。

三、代表性論文

Publications prior joining HBU:

9. Catalytic asymmetric acetalization of carboxylic acids for access to chiral phthalidyl ester prodrugs.Yingguo Liu, Qiao Chen, Chengli Mou, Lutai Pan, Xiaoyong Duan, Xingkuan Chen, Hongzhong Chen, Yanli Zhao, Yunpeng Lu, Zhichao Jin, Yonggui Robin Chi*Nature Communications volume 10, Article

number: 1675 (2019, DOI:10.1038/s41467- 019-09445-x)(https://www.nature.com/articles/s41467-019-09445-x)

8. Hydrazonyl Radical-Participated Tandem Reaction: A Strategy for the Synthesis of Pyrazoline- Functionalized OxindolesXiao-Yong Duan, Xiu-Long Yang, Pan-Pan Jia, Man Zhang, and Bing Han*Org. Lett., 2015, 17, 6022–6025.(https://pubs.acs.org/doi/abs/10.1021/acs.orglett.5b03003?

journalCode=orlef7&quickLinkVolume=17&quickLinkPage=6022&selectedTab=citation&volume=17)

7. N-heterocyclic carbene-catalyzed stereoselective annulations: An efficient strategy for the synthesis of chromeno [4, 3-b] pyrrolidine derivatives.Jing Qi*, Xiao-Yong Duan, Li-Li Cao, Wen-Ying WangAsian J. Org. Chem., 2015, 4, 1254 –1257.(https://onlinelibrary.wiley.com/doi/10.1002/ajoc.201500266)

6. Transition from π Radicals to σ Radicals: Substituent-Tuned Cyclization of Hydrazonyl RadicalsXiao-Yong Duan, Neng-Neng Zhou, Ran Fang, Xiu-Long Yang, Wei Yu, and Bing Han*.Angew. Chem. Int. Ed., 2014, 53, 3158 –3162.(https://onlinelibrary.wiley.com/doi/10.1002/anie.201309918)

5. Hydrazone Radical Promoted Vicinal Difunctionalization of Alkenes and Trifunctionalization of Allyls: Synthesis of Pyrazolines and TetrahydropyridazinesXiao-Yong Duan, Xiu-Long Yang, Ran Fang, Xie-Xue Peng, Wei Yu, and Bing Han*J. Org. Chem., 2013, 78, 10692-10704

://pubs.acs.org/doi/abs/10.1021/jo4016908?journalCode=joceah&quickLinkVolume=78&quickLinkPage=10692&selectedTab=citation&volume=78)

4. Oxime Radical Promoted Dioxygenation, Oxyamination, and Diamination of Alkenes: Synthesis of Isoxazolines and Cyclic Nitrones.Bing Han*, Xiu-Long Yang, Ran Fang, Wei Yu, Chao Wang, Xiao-Yong Duan, Shuai LiuAngew. Chem. Int. Ed., 2012, 51, 8816.

(https://onlinelibrary.wiley.com/doi/10.1002/anie.201203799)

3. Efficient aerobic oxidative synthesis of 2-aryl quinazolines via benzyl C–H bond amination catalyzed by 4-hydroxy-TEMPOBing Han*, Chao Wang, Run-Feng Han, Wei Yu,* Xiao-Yong Duan, Ran Fang and Xiu-Long YangChem. Commun., 2011, 47, 7818-7820.

(https://pubs.rsc.org/en/content/articlelanding/2011/cc/c1cc12308d#!divAbstract)

2. Efficient aerobic oxidative dehydrogenation of dihydropyrimidinones and dihydropyrimidinesBing Han*, Run-Feng Han, Yu-Wei Ren, Xiao-Yong Duan, Yi-Chuan Xu, Wei ZhangTetrahedron 2011, 67, 5615–5620.(https://www.sciencedirect.com/science/article/pii/S0040402011007952)

1. Photoinduced Intramolecular Addition of 3-Acyl-2-haloindoles to AlkenesShen-Ci Lu, Xiao-Yong Duan, Zong-Jun Shi, Bing Li, Yu-Wei Ren, Wei Zhang*, Yong-Hui Zhang and Zhi-Feng TuOrg. Lett., 2009, 11, 3902–3905.(https://pubs.acs.org/doi/abs/10.1021/ol901498f?

journalCode=orlef7&quickLinkVolume=11&quickLinkPage=3902&selectedTab=citation&volume=11)

四、科研項目

1. 河北大學科研啟動經費，801260201299，腙自由基參與的烯烴的官能團化研究，2018.11-2021.10;

2. 2019年河北省自然科學基金-青年科學基金項目，B2019201101，腙自由基參與的含氮雜環化合物的合成研究，2019.09-2022.08;

3. 2019年度河北省引進留學人員資助項目，C20190503，雜原子自由基參與的雜環化合物的對映選擇性合成, 2019.08-2022.07;